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photograph by Arenamontanus, flickr.com

 
Issue no. 21, 2010
Published: Jun 25, 2010

Hot electrons could double solar cell efficiency
Memories made of light
Sub-atomic particle signals simulated as sound
'Dark pulse laser' could improve telecoms
Researchers develops green process for producing fuel additive
Electron 'invisible ink' promises purer nanocrystals
Zap of UV light may have triggered life

Hot electrons could double solar cell efficiency
The most efficient silicon solar cells turn 25% of the incoming light into electricity, but even with further improvements these cells will reach a theoretical limit at 31%, because incoming light creates large numbers of extremely energetic electrons. These 'hot' electrons lose their energy in less than a picosecond - too rapidly to be harnessed.

Previous research suggested that nanoscale chunks of semiconducting material could help slow the rate at which hot electrons lose energy as heat. That's because the energy levels within quantum dots are widely spaced, making it difficult for electrons to jump between them. The energy levels are more closely packed in larger chunks of semiconductor such as the silicon wafers often used in solar cells, so jumping levels and losing energy as heat is easier.

Now, researchers at the University of Texas in Austin have shown that those longer-lived hot electrons can pass from quantum dots to a semiconducting wafer before the electrons give up their energy as heat - a step towards a solar cell that can harness hot electrons for their energy, boosting the theoretical maximum efficiency to 66%. The researchers coated a wafer of semiconducting titanium dioxide with quantum dots of lead selenide and shone light on it. A change in the optical properties of the wafer showed that electrons had entered it from the quantum dots. But the materials were engineered such that the electrons could enter the substrate only when hot.
New Scientist / Science    Jun 24, 2010 back to top

Memories made of light
Researchers have coaxed laboratory crystals to capture and release information carried within a light pulse at the highest efficiency yet.

Light is the ideal carrier of information, because it is so fast. Until now, researchers have tried to fashion 'quantum memories' for light primarily by sending lasers into a vapour made of atoms. The atoms preserve information in the light that can then be read out again. But quantum memories based on atomic vapours are inefficient. The best such system reported to date has an efficiency of 17%. A system needs at least 50% recall to be useful in quantum applications.

The new work by researchers at the Australian National University in Canberra instead uses a solid crystal, in which the atoms are rigidly packed together instead of bouncing around diffusely as they would in a vapour. That control helps to achieve a memory efficiency of 69%.

As the light pulse enters the crystal, it begins to slow down, its front reaching one end of the crystal and stopping as the rest of the light squeezes itself in. The crystal is mostly transparent but can absorb one particular colour very strongly. The researchers switch on an electric field gradient, which changes the strongest absorption colour in different parts of the crystal, so that one end of it absorbs strongly at the blue end of the spectrum and the other end toward the red. Quantum information from the light is stored in the oscillations of the crystal's atoms. Reversing the electric field causes the atoms to re-emit light containing the same information as the original pulse.
ScienceNews / Nature    Jun 23, 2010 back to top

Sub-atomic particle signals simulated as sound
Scientists have simulated the sounds set to be made by sub-atomic particles such as the Higgs boson when they are produced at the Large Hadron Collider (LHC). Their aim is to develop a means for physicists at CERN to 'listen to the data' and pick out the Higgs particle if and when they finally detect it.

The researchers modelled data from the giant Atlas experiment at the LHC, converting data expected from collisions at the LHC into sounds. Atlas is one of the experiments at the LHC. An instrument inside Atlas called the calorimeter is used for measuring energy and is made up of seven concentric layers. Each layer is represented by a note and their pitch is different depending on the amount of energy that is deposited in that layer. The process of converting scientific data into sounds is called sonification.

The researchers have so far generated a number of simulations based on predictions of what might happen during collisions inside the LHC. The team is only now feeding in real results from real experiments. The aim is to give physicists at the LHC another way to analyse their data. The sonification team believes that ears are better suited than eyes to pick out the subtle changes that might indicate the detection of a new particle.
BBC News    Jun 22, 2010 back to top

'Dark pulse laser' could improve telecoms
A new type of laser that emits 'dark' pulses could provide better signals for telecommunications, according to physicists at the National Institute of Standards and Technology (NIST) in the US who have created the device. The dark pulses, which consist of intensity dips in an otherwise continuous beam of laser light, are effectively the opposite of the bright bursts in a normal pulsed laser.

Dark lasers are not entirely new. For some 20 years, physicists have been able to create so-called dark soliton lasers. Solitons are light pulses that propagate without spreading, and are often used in fibre optics. Their dark counterparts are simply gaps in a continuous beam that do not spread either. But dark solitons are difficult to create and, when they are created, it is done outside the laser using a combination of tricky pulse-shaping techniques. The new dark pulse laser, on the other hand, forms the dark pulses inside the laser itself.

The researchers suggest that the dark pulse laser could find applications in telecommunications, because the dark pulses are less prone to disperse than regular, bright pulses.
PhysicsWorld / Optics Express    Jun 16, 2010 back to top

Researchers develops green process for producing fuel additive
A new green, bio-based method for producing a much-used fuel additive and industrial chemical that is currently made from petroleum products has been developed by researchers at Iowa State University. They invented a process for manufacturing isobutene or isobutylene by identifying a new, natural enzyme that produces the fuel organically.

The enzyme makes it possible to convert the glucose found naturally in plants to make isobutene. The enzyme is found naturally in about half of all organisms in the world. Isobutene is a gas used to produce chemicals and also in the manufacturing of fuel additives, adhesives, plastics and synthetic rubber. It can be chemically converted to isooctane, which is a fuel that could be used to replace gasoline additive methyl tert-butyl ether (MBTE), which can be environmentally harmful.

Isooctane is used in gasoline to stop engine knocking and other problems. Currently, isooctane is produced from petroleum products. By using his naturally occurring, biological process to produce isobutene, the researchers believes there will be environmental and cost benefits to the biofuels industry.
PhysOrg / Iowa State University     Jun 23, 2010 back to top

Electron 'invisible ink' promises purer nanocrystals
By its very nature, nanotechnology is too small to see with the naked eye. Even so, chemists at the University of Erlangen-Nuremberg in Germany have found a way to make it even less perceptible by creating a nanoscopic form of 'invisible ink'. The technique offers a way of growing nanocrystals of a much higher purity than achieved to date.

The researchers used an electron beam to remove oxygen ions from a silicon oxide wafer, leaving nanoscopic dents in the surface. The process leaves virtually no visible trace. The dents facilitate chemical reactions, though, so a hidden message written onto the wafer with the electron beam can later be revealed by flowing iron pentacarbonyl gas across the surface.

The gas reacts at the indentations to form carbon monoxide while leaving solid - and reflective - iron nanocrystals fixed to the surface. The process leaves virtually no visible trace, but the hidden message can later be revealed.
New Scientist / Angewandte Chemie International    Jun 23, 2010 back to top

Zap of UV light may have triggered life
A blast of ultraviolet light may have helped create an important molecular building block for life, say scientists from Georgia Tech in Atlanta and the University of Roma 'La Sapienza'.

The researchers focused on the molecule formamide, the simplest structure containing the required four building blocks of life - carbon, hydrogen, oxygen and nitrogen. Previous studies have already shown how heating formamide in a mineral stew creates most of the ingredients for ribonucleic acid, commonly known as RNA. RNA is thought to have served as an early operating system for life, later joined by the more robust deoxyribonucleic acid, or DNA, genetic coder.

Missing from the formamide brew, however, has been guanine, one of RNA's four critical ingredients (the others are adenine, cytosine and uracil.) One lightning rod for guanine's creation, scientists discovered, is ultraviolet light. Today, Earth's atmosphere blocks most UV rays from the sun, but in its early years the planet lacked ozone and other shielding chemicals in its skies. The research demonstrates a scenario for creating RNA that would not require lots of heat or standing pools of liquid water. The finding could also mean conditions for life elsewhere in the solar system may not be as stringent.

Scientists are now working to mimic the day-night cycles of solar ultraviolet radiation and adding different minerals to see how that changes the resulting RNA brew.
ABC / ChemBioChem    Jun 16, 2010 back to top
 
         
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