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Lithium. Photograph: http://www.periodictable.com

 
Issue no. 10, 2009
Published: Mar 13, 2009

New batteries recharge in seconds
Coatings that 'self-heal' in sun
Internet at risk from 'wiretapping', says web inventor
Society's vital networks prone to 'explosive' changes
Device turns pink before you do

New batteries recharge in seconds
MIT engineers have found a way to make lithium batteries that are smaller, lighter, longer lasting and capable of recharging in seconds. The researchers believe the quick-charging batteries could open up new applications, including better batteries for electric cars. And because they use older materials in a new way, the batteries could be available for sale in two to three years.

Current rechargeable lithium batteries can store large amounts of energy, making them long-running. But they are stingy about releasing their power, making them discharge energy slowly and require hours to recharge. Scientists traditionally have blamed slow-moving lithium ions - which carry charge across the battery - for this sluggishness.

However, about five years ago MIT scientists discovered that lithium ions in traditional lithium iron phosphate battery material actually move quite quickly. They found that lithium ions travel through tunnels accessed from the surface of the material. If a lithium ion at the surface is directly in front of a tunnel entrance, it can quickly deliver a charge. But if the ion is not at the entrance, it cannot easily move there, making it less efficient at delivering a charge.

The team remedied this by revamping the battery recipe. This created many smooth tunnels in the material that allow the ions to slip in and out easily. Using their new processing technique, the team made a small battery that could be fully charged in 10 to 20 seconds.
Reuters / Nature    Mar 12, 2009 back to top

Coatings that 'self-heal' in sun
Scientists at the University of Southern Mississippi have devised a coating that when scratched heals itself upon exposure to sunlight.

The secret of the material lies in using molecules made from chitosan, which is derived from the shells of crabs and other crustaceans. In the event of a scratch, ultraviolet light drives a chemical reaction that patches the damage.

The researchers designed molecules joining ring-shaped molecules called oxetane with chitosan. The custom-made molecules were added to a standard mix of polyurethane, a popular varnishing material that is also used in products ranging from soft furnishings to swimsuits.

Scratches or damage to the polyurethane coat split the oxetane rings, revealing loose ends that are highly likely to chemically react. In the ultraviolet light provided by the sun, the chitosan molecules split in two, joining to the oxetane's reactive ends. The researchers found their coatings were able to fully heal themselves in just 30 minutes.
BBC News / Science    Mar 12, 2009 back to top

Internet at risk from 'wiretapping', says web inventor
The ever-increasing power of computers that is helping the internet to grow is also threatening its future. That was the warning delivered by Tim Berners-Lee, the web's inventor, and online security specialists at the Houses of Parliament in London this week. Their concerns are centred on deep packet inspection (DPI), a technique that makes it possible to peer inside packets of data transmitted across the internet.

DPI is already being used for commercial gain, without the consent of users. Companies try to sell DPI-acquired data to firms that can use it - for example, to target online adverts. DPI is also used by the Chinese government to enforce its web censorship programme, sometimes called the Great Firewall of China.

Berners-Lee has no issue with targeted adverts, which he said offered online users an improved service, but is uncomfortable with using DPI to provide them. He likened DPI to wiretapping, and pointed out that companies could use it to learn a huge amount about our 'lives, hates and fears'. One example he gave was that the web is often the first point of call for people with health concerns.

DPI has become possible thanks to improvements in computing power, which allows internet servers to relay data and simultaneously snoop inside data packets. Until recently that was beyond the capabilities of the available technology.
New Scientist    Mar 11, 2009 back to top

Society's vital networks prone to 'explosive' changes
Computer scientists at the University of California have found that random networks - the mathematical description for networks we experience everyday in forms such as the internet and global flight connections - have the potential for extreme behaviour never seen before. Their findings might lead to improved understanding of how to control such networks - for example, to halt the spread of epidemics or improve the efficiency of delivery networks.

The researchers have been playing a Buckaroo-style game, adding more and more connections between nodes in a network to see what happens. Networks that grow randomly - such as the internet - usually rapidly and smoothly gain a central backbone of connections that make it simple to travel between any two points in a fully connected structure. The team has used simulations to find a way to grow a network randomly, but significantly delay the emergence of that backbone. But rather like the mule in Buckaroo, when the network does become fully connected it is with an explosive kick rather than a gradual change.

Random networks are usually grown by selecting two nodes at random to become connected. Instead the team pick two pairs of random nodes, but only connect one of them - the pair with the fewest pre-existing connections to other nodes. The result is that for a long time the network grows, but does not become fully connected. Instead it contains a large number of unconnected chunks. Eventually, the addition of just one link triggers an instantaneous phase change and the network becomes fully connected.
New Scientist / Science    Mar 13, 2009 back to top

Device turns pink before you do
Researchers at the University of Strathclyde, UK, have developed an indicator that turns an appropriate shade of pink to alert wearers of sunburn. The thin film device could be worn as a wrist band to warn wearers they risk receiving a potentially harmful dose of UV rays.

UV rays drive a chemical reaction in the indicator, releasing an acid into a dye, and causing it to change colour. Other indicators are already available that detect and measure UV. But what is special about the new one is that it can be adjusted to give an instant signal at the point when sun exposure is about to cause damage, according to its inventors.

The researchers have made a prototype of the film, combining a dye that gradually changes colour from yellow to blue, and a central strip of dye that turns pink. The device could also be adapted to different skin types; adding an alkali to the dye would increase the delay before the colour change.
BBC News / Chemical Communications    Mar 12, 2009 back to top
 
         
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